AustralieFrV1, Main, Exploration, bibRecord, 009324

Synthesis and electrochemical properties of V2O5nanostructures prepared via a precipitation process for lithium-ion battery cathodes

Identifieur interne : 009324 ( Main/Exploration ); précédent : 009323; suivant : 009325

Synthesis and electrochemical properties of V2O5nanostructures prepared via a precipitation process for lithium-ion battery cathodes

Auteurs : S. H. Ng [Australie] ; S. Y. Chew [Australie] ; J. Wang [Australie] ; D. Wexler [Australie] ; Y. Tournayre [Australie] ; K. Konstantinov [Australie] ; H. K. Liu [Australie]

Source :

Journal of power sources [ 0378-7753 ] ; 2007.

RBID : Pascal:08-0329556

Descripteurs français

Pascal (Inist)
- Propriété électrochimique, Batterie lithium, Cathode, Nanostructure, Oxyde de vanadium, Diffractométrie RX, Microscopie électronique balayage, Voltammétrie cyclique, Cycle charge décharge, Durée service, Accumulateur électrochimique.

English descriptors

KwdEn :
- Cathode, Cyclic voltammetry, Discharge charge cycle, Electrochemical properties, Lithium battery, Nanostructure, Scanning electron microscopy, Secondary cell, Service life, Vanadium oxide, X ray diffractometry.

Abstract

One-dimensional (1D) nanostructures of vanadium pentoxide (V₂O₅) have been successfully synthesized via a precipitation process followed by heating in vacuum at 300 °C. The samples have been characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), and electrochemical testing by techniques such as cyclic voltammetry (CV) and discharge-charge cycling in lithium cells. Average crystal size of these oxides increased from 36 to 83 nm as annealing time was increased from 45 min to 1 h, which also led to a decrease in Brunauer-Emmett-Teller (BET) specific surface area from 41 to 17m² g^-1. Good cyclability and high capacity (>200 mAh g^-1) were achieved in the voltage range of 2.0-4.0V (versus Li metal) at a current rate of 50 mA g^-1 by annealing the oxides for 1 h. The increase in crystallinity and higher yield of one-dimensional nanostructure oxides contributed significantly to the improved capacity and enhanced cycle life.

Affiliations:

Australie

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Le document en format XML

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<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Cathode</term>
<term>Cyclic voltammetry</term>
<term>Discharge charge cycle</term>
<term>Electrochemical properties</term>
<term>Lithium battery</term>
<term>Nanostructure</term>
<term>Scanning electron microscopy</term>
<term>Secondary cell</term>
<term>Service life</term>
<term>Vanadium oxide</term>
<term>X ray diffractometry</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr"><term>Propriété électrochimique</term>
<term>Batterie lithium</term>
<term>Cathode</term>
<term>Nanostructure</term>
<term>Oxyde de vanadium</term>
<term>Diffractométrie RX</term>
<term>Microscopie électronique balayage</term>
<term>Voltammétrie cyclique</term>
<term>Cycle charge décharge</term>
<term>Durée service</term>
<term>Accumulateur électrochimique</term>
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<front><div type="abstract" xml:lang="en">One-dimensional (1D) nanostructures of vanadium pentoxide (V<sub>2</sub>
O<sub>5</sub>
) have been successfully synthesized via a precipitation process followed by heating in vacuum at 300 °C. The samples have been characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), and electrochemical testing by techniques such as cyclic voltammetry (CV) and discharge-charge cycling in lithium cells. Average crystal size of these oxides increased from 36 to 83 nm as annealing time was increased from 45 min to 1 h, which also led to a decrease in Brunauer-Emmett-Teller (BET) specific surface area from 41 to 17m<sup>2</sup>
 g<sup>-1</sup>
. Good cyclability and high capacity (>200 mAh g<sup>-1</sup>
) were achieved in the voltage range of 2.0-4.0V (versus Li metal) at a current rate of 50 mA g<sup>-1</sup>
 by annealing the oxides for 1 h. The increase in crystallinity and higher yield of one-dimensional nanostructure oxides contributed significantly to the improved capacity and enhanced cycle life.</div>
</front>
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<name sortKey="Chew, S Y" sort="Chew, S Y" uniqKey="Chew S" first="S. Y." last="Chew">S. Y. Chew</name>
<name sortKey="Konstantinov, K" sort="Konstantinov, K" uniqKey="Konstantinov K" first="K." last="Konstantinov">K. Konstantinov</name>
<name sortKey="Konstantinov, K" sort="Konstantinov, K" uniqKey="Konstantinov K" first="K." last="Konstantinov">K. Konstantinov</name>
<name sortKey="Liu, H K" sort="Liu, H K" uniqKey="Liu H" first="H. K." last="Liu">H. K. Liu</name>
<name sortKey="Liu, H K" sort="Liu, H K" uniqKey="Liu H" first="H. K." last="Liu">H. K. Liu</name>
<name sortKey="Ng, S H" sort="Ng, S H" uniqKey="Ng S" first="S. H." last="Ng">S. H. Ng</name>
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<name sortKey="Wang, J" sort="Wang, J" uniqKey="Wang J" first="J." last="Wang">J. Wang</name>
<name sortKey="Wang, J" sort="Wang, J" uniqKey="Wang J" first="J." last="Wang">J. Wang</name>
<name sortKey="Wexler, D" sort="Wexler, D" uniqKey="Wexler D" first="D." last="Wexler">D. Wexler</name>
</country>
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Synthesis and electrochemical properties of V2O5nanostructures prepared via a precipitation process for lithium-ion battery cathodes

Synthesis and electrochemical properties of V2O5nanostructures prepared via a precipitation process for lithium-ion battery cathodes

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